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991.
B(H)表示定义在希尔伯特空间H上的所有有界线性算子的全体。对于A∈B(H),其中σ(A)和W(A)分别表示算子A的谱和数值域,N表示自然数集。关于算子A的n(n∈N)次方根,本文的主要结果是:(1)若σ(A)∩(-∞,0]=φ,则A有惟一的n次方根B∈B(H)且σ(B)(?)~(2/n)~o;(2)若(?)∩(-∞,0]=φ,则A有惟一的n次方根B∈B(H)且(?)(2/n)~o这里,S_(1/n)={λ∈C‖argλ|≤(1/2n)π}且S_(1/n)~o表示集合S+(1/n)的内部。 相似文献
992.
利用推广的Hartle-Hawking假设,研究了4+2D维Einstein-Maxwell量子宇宙,计算了微超空间波函数的近似解.发现当D≤2时存在与观测宇宙相符合的暴胀解. 相似文献
993.
用TG-DTA,高温X-射线衍射研究了稀土间硝基苯甲酸配合物LnL_3·nH_2O(n=2,Ln=La→Lu+Y;n=0,Ln=Sc,HL=间硝基苯甲酸)的热分解行为,DSC测定其脱水相变过程中的热力学函数,同时用透射电镜观察了热分解产物的超微性。 相似文献
994.
995.
烷基苯的热力学性质与分子拓扑指数的关系研究 总被引:6,自引:0,他引:6
倪才华 《原子与分子物理学报》1995,12(2):213-218
此文分析了烷基苯的结构特点,以分子的拓扑指数为结构参数,研究了苯、烷基系列的燃烧热,生成自由能等八种热力学性质与结构参数的关系,提出计算热力学性质的一个通用关系式Y=a·N+b·R+c·NR+d,用计算机处理,得到一系列经验公式,计算结果表明:烷基苯系列的热力学性质与拓扑指数相关性能很好。 相似文献
996.
Diagnosis of phasma in CCD damage process induced by laser 总被引:1,自引:0,他引:1
In this paper, the shapes of plasma produced by a Q-switched YAG laser acted repeatedly upon a CCD with MOS structure are used, to investigate the destroying process of the optoelectronic device. The experimental results of CCD destroyed by a 1.06μm laser beam with a pulse width of 15 ns are given. 相似文献
997.
ZHANG Zhenyue & DU Keqin Department of Mathematics Zhejiang University Hangzhou China. 《中国科学A辑(英文版)》2006,49(7):971-986
We present a successive projection method for solving the unbalanced Procrustes problem: given matrix A∈Rn×n and B∈Rn×k, n>k, minimize the residual‖AQ-B‖F with the orthonormal constraint QTQ = Ik on the variant Q∈Rn×k. The presented algorithm consists of solving k least squares problems with quadratic constraints and an expanded balance problem at each sweep. We give a detailed convergence analysis. Numerical experiments reported in this paper show that our new algorithm is superior to other existing methods. 相似文献
998.
Supramolecular inclusion complexes (ICs) involving polyhedral oligomeric silsesquioxane (POSS) capped poly(?‐caprolactone) (PCL) and α‐cyclodextrin (α‐CD) were investigated. POSS‐terminated PCLs with various molecular weights were prepared via the ring‐opening polymerization of ?‐caprolactone (CL) with 3‐hydroxypropylheptaphenyl POSS as an initiator. Because of the presence of the bulky silsesquioxane terminal group, the inclusion complexation between α‐CD and the POSS‐capped PCL was carried out only with a single end of a PCL chain threading inside the cavity of α‐CD, which allowed the evaluation of the effect of the POSS terminal groups on the efficiency of the inclusion complexation. The X‐ray diffraction results indicated that the organic–inorganic ICs had a channel‐type crystalline structure. The stoichiometry of the organic–inorganic ICs was quite dependent on the molecular weights of the POSS‐capped PCLs. With moderate molecular weights of the POSS‐capped PCLs (e.g., Mn =3860 or 9880), the stoichiometry was 1:1 mol/mol (CL unit/α‐CD), which was close to the literature value based on the inclusion complexation of α‐CD with normal linear PCL chains with comparable molecular weights. When the PCL chains were shorter (e.g., for the POSS‐capped PCL of Mn = 1720 or 2490), the efficiency of the inclusion complexation decreased. The decreased efficiency of the inclusion complexation could be attributed to the lower mobility of the bulky POSS group, which restricted the motion of the PCL chain attached to the silsesquioxane cage. This effect was pronounced with the decreasing length of the PCL chains. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1247–1259, 2007 相似文献
999.
The carbides of NdDy0.2Fe12-yMoyC0.6 (y = 1.5, 2) crystallized in the ThMn12-type structure have been successfully synthesized by arc melting method, followed by a heat treatment. The magnetic properties are strongly enhanced with the addition of carbon. Upon the carbonation the saturation magnetization Ms is increased by about 20emu/g and the Curie temperature Tc is enhanced by 40-70K. The spin reorientation (SR) temperature decreases from 125 K for NdDy0.2Fe10Mo2 to 55 K for NdDy0.2Fe10MO2C0.6 indicating the change of magnetocrystalline anisotropy in the Nd sublattice. It is found that the intrinsic magnetic properties of the carbides can be improved by further nitrogenation, The composite carbon-nitrogen compounds show a Tc - 560K, M8 - 105 emu/g and Ha (anisotropy field) - 86kOe for NdDy0.2Fe10Mo2Co.6Nz and a Tc- 628K, M8 - 119 emu/g and Ha - 115kOe for NdDy0.2Fe10.5Mo1.5C0.6Nz. These magnetic properties are even better than those of simple nitrides, suggesting that these compounds can be considered as a good candidate for permanent magnet applications. 相似文献
1000.
EFFECT OF THERMAL TREATMENTS ON THE SUPERCONDUCTIVITY OF UNDOPED AND WO3 DOPED Y-Ba-Cu-O SYSTEM 下载免费PDF全文
Undoped and WO3-doped Y-Ba-Cu-O ceramics have been slowly cooled in flowing oxygen or quenched in air from 900℃ to room temperature, after sintering at 900℃ for 3Oh in flowing oxygen. The ac susceptibility measurements show that the Tc of the quenched WO3-doped Y-Ba-Gu-O superconductor can reach 88K, while the undoped Y-Ba-Cu-O ceramic quenched in air is a non-superconductor. X-ray diffraction data show that WO3 does not enter into the YBa2Cu3O7-x lattice but forms all impurity phase. The WO3-doped YBCO specimens quenched in air consist of orthorhombic YBa2Cu3O7-x phase and an impurity phase which increases with increasing WO3 content. Raman spectra chow that oxygen contents are different for undoped and WO3-doped samples. It la suggested that suitable doping with WO3 can change the oxygen content and reduce the effect of thermal treatments on the superconductivity of Y-Ba-Cu-O system. 相似文献